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Q.

X and Y are two volatile liquids.  X and Y are mixed in the mole ratio 1 : 3 to form an ideal solution of a total vapour pressure of 550 mm when one mole of B is added to this mixture the total vapour pressure increased by 10 mm.  The vapour pressures of pure liquids A and B respectively is

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a

600, 400

b

400, 600

c

420, 640

d

640, 420 

answer is C.

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Detailed Solution

nAnB=13

PA0XA+PB0XB=PS

x×14+y×34=550      x+3y=2200

x×15+y×45=560      x+4y=2800

x = 400, y = 600

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X and Y are two volatile liquids.  X and Y are mixed in the mole ratio 1 : 3 to form an ideal solution of a total vapour pressure of 550 mm when one mole of B is added to this mixture the total vapour pressure increased by 10 mm.  The vapour pressures of pure liquids A and B respectively is