Q.

'x' g of molecular oxygen O2 is mixed with 200 g of neon (Ne). The total pressure of the nonreactive mixture of Oand Ne in the cylinder is 25 bar. The partial pressure of Ne is 20 bar at the same temperature and volume. The value of 'x' is_____. [Given: Molar mass of O2=32gmol−1. Molar mass of Ne=20gmol−1J

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answer is 80.

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Detailed Solution

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Given:

  • Total pressure, Ptotal = 25 bar
  • Partial pressure of neon, PNe = 20 bar

PO₂ = Ptotal - PNe

PO₂ = 25 bar - 20 bar = 5 bar

The mole fraction (xi) of a gas is given by:

xi = Pi / Ptotal

For neon:

xNe = PNe / Ptotal = 20 / 25 = 0.8

For oxygen:

xO₂ = PO₂ / Ptotal = 5 / 25 = 0.2

The molar mass of neon (Ne) is 20 g/mol. Thus:

nNe = mass of Ne / molar mass of Ne

nNe = 200 g / 20 g/mol = 10 mol

Since the mole fraction of neon is 0.8:

ntotal = nNe / xNe

ntotal = 10 mol / 0.8 = 12.5 mol

nO₂ = ntotal × xO₂

nO₂ = 12.5 mol × 0.2 = 2.5 mol

The molar mass of oxygen (O₂) is 32 g/mol. Thus:

Mass of O₂ = nO₂ × molar mass of O₂

Mass of O₂ = 2.5 mol × 32 g/mol = 80 g

Final Answer:

The mass of molecular oxygen in the mixture is 80 grams.

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