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Q.

“X” is the best reducing agent among the hydrides of 15th group and ‘Y’ is the most volatile 15th group hydride. X & Y respectively are

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a

SbH3,NH3

b

NH3,  PH3

c

BiH3,  PH3

d

BiH3,NH3

answer is C.

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Detailed Solution

Reducing power ….    NH3<PH3<AsH3<SbH3<BiH3…….down the group as X - H bond enthalpy decreases , reducing power increases

Boiling point           ….   PH3<AsH3<NH3<SbH3<BiH3

Boiling point  α  1volatility

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