Q.

x mol N2O4  is taken at P1  atm in a closed vessel & heated. When 75% N2O4  dissociated at equilibrium, total pressure is found to be P2  atm. The relation between P1&P2  is

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a

P1:P2=7:2

b

P1:P2=4:7

c

P1:P2=3:4

d

P1:P2=7:4

answer is C.

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Detailed Solution

N2O42NO2

x0

0.75x1.5x_

0.25x1.5x

GivenxmolesP11.75xmolesP2

         P1P2=n1n2=x1.75x=47   

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