Q.

 'X+CuSO4I2Na2S2O3+ White ppt. [Y] 

    NaI+[Z]    colourless compound.

Here, compound [Z] :

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a

Cu2S2O3

b

Cu2I2

c

Na2S4O6

d

Na4Cu6S2O35

answer is C.

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Detailed Solution

Copper sulphate in reaction with potassium iodide gives following reaction,

2CuSO4+4KI2CuI+I2+2K2SO4

Potassium sulphite is a white, water-soluble solid with the chemical formulaK2SO4.

It frequently serves as a potassium and sulphur source for fertilisers.

I2+Na2S2O3NaI+Na2S4O6 [colleurless compound.] 

While Na2S4O6 (Sodium tetrathionate) is a colourless compound.

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 'X+CuSO4⟶I2↓Na2S2O3+ White ppt. [Y]     NaI+[Z]    colourless compound.Here, compound [Z] :