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Q.

Xenon trioxide,  XeO3 reacts with aqueous base to form the Xenon containing anion. This ion reacts further with OH- to form the perxenate anion XeO64  in the following reaction:2HXeO4(aq)+2OH(aq)XeO64(aq)+Xe+O2(g)+2H2O
In this reaction: 

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a

Xenon is both oxidized and reduced

b

Oxygen in  OH is oxidized.

c

The electrons required for the reduction of one xenon atom are supplied by both, another xenon atom and OH- ions.

d

In the conversion of 2 moles of HXeO4 to  Xe and  XeO64, the net electrons required are 4

answer is A, B, C, D.

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Detailed Solution

 Question Image
 Question Image
In the first step xenate ion HXeO4  is formed. In the second step it undergoes both oxidation and reduction. In the second step the perxenate ion  XeO64 is formed in which Xe oxidation number is +8 and the second Xe is reduced to Xe. In addition O2- is oxidized to O2.
One Xe atom in HXeO4  loses 2 electrons to convert into  HXeO64. Second Xe atom in  HXeO4 gains 6 electrons to give Xe. Thus 2 HXeO4ions require a net 4 electrons. These electrons can be supplied by the oxidation of 2O2 ions to give O2.   Structure of perxenate ion is
 

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