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Q.

x m mol of KIO3 reacts completely with y m mol of KI to give I2 quantitively. If z m mol of hypo are  required for complete titration against this I2, then, which statement is incorrect?

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a

z=6x

b

5x=y

c

6y=5z

d

x+y=2z

answer is D.

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Detailed Solution

The reaction is,

KIO3+5KI3I2

x            y       Z2=3x=3y5

n factor for  KIO35

n factor for KI1

n factor for 125/3

Here, 5x=y

Also, 

I2+2Na2S2O3Na2S4O6+2NaI

Z Z2

With these values, the relation given in option D becomes incorrect.

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