Q.

 ZMA(g)Z4M8B(g)+(α particles )

(α. particles are helium nuclei, so will form He gas by trapping electrons). The radioactive disintegrations follows 1st order kinetics, starting with 1 mole of A in a 16.4 litre closed flask at 127° Pressure (atm) developed after two half lives is: (R = 0.082 litre atm/mol-K)

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answer is 5.

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Detailed Solution

Given reaction is,

 ZMA(g)Z4M8B(g)+(α particles )

R = 0.082 litre atm/mol-K

Pressure (atm) developed after two half lives is 5 atm for this case.

p=n×R×TV p=0.25×0.82×40016.4 p=5 atm

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