$\mathrm{Zn}+{\mathrm{Cu}}_{\left(\mathrm{aq}\right)}^{2+}⟶\mathrm{Cu}+{\mathrm{Zn}}_{\left(\mathrm{aq}\right)}^{2+}$ reaction quotient, $\mathrm{Q}=\frac{\left[{\mathrm{Zn}}^{2+}\right]}{\left[{\mathrm{Cu}}^{2+}\right]}\text{ variation of }{\mathrm{E}}_{\text{cell }}$with log Q is of the type with $\mathrm{OA}=1.10\mathrm{V},{\mathrm{E}}_{\text{cell }}\text{ will be }1.1591\mathrm{V}\text{ when }$