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Q.

  Zn(s)+Cu(aq)+Zn(aq)2++Cu(s);ΔG=-XKJ   Cu(s)+2Ag(aq)+2Ag(s)+Cu(aq)2+;ΔG=-YKJ    then ΔG for Zn(s)+2Ag(aq)+2Ag(s)+Zn(aq)2+ will be (in KJ

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a

-(X+Y)

b

(Y-X)

c

2(X-Y)

d

X-Y2

answer is A.

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Detailed Solution

  Zn(s)+Cu(aq)+Zn(aq)2++Cu(s)+;ΔG=-XKJ   Cu(s)+2Ag(aq)+2Ag(s)+Cu(aq)2+;ΔG=-YKJ 1

Now, on subtracting equation 2 from equation 1.

We get, Zn(s)+2Ag(aq)+2Ag(s)+Zn(aq)2+

The Gibbs free energy for this equation is ΔG=-X-(-Y)=-(X+Y) or (Y-X)

Hence, ΔG=-(X+Y)

Therefore, option (A) is correct.

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