DNA polymerase catalyzes the polymerization of nucleotides in the following direction.
3′ → 3′ direction
5′ → 5′ direction
3′ → 5′ direction
5′ → 3′ direction
DNA polymerase forms daughter DNA strand on template DNA strand in 5′ → 3′ direction because the template DNA strand is with 3′ → 5′ polarity.