Q.
‘A’ and ‘B’ are two volatile liquids.A mixture of ‘A’ and'B' is prepared.A graph is plotted between vapour pressure of liquid mixture and mole fraction. The following plot is obtainedFrom the graphical represent identify the liquid mixture
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a
C6H14+C7H16
b
HNO3+H2O
c
C2H5OH+CS2
d
C6H5NH2+C6H5OH
answer is C.
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Detailed Solution
From the graph it is evident that A) ptotal>pA+pBB) pA>pAoxAC) pB>pBoxBThe liquid mixture shows positive deviations from Raoult's law.The H-bonds of C2H5OH are weakened by the addition of CS2. A-B interactions are weaker than A-A and B-B interactions.
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