ΔfGΘ vs T plot in the Ellingham diagram slopes downward for the reaction
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a
Mg+12O2⟶MgO
b
2Ag+12O2⟶Ag2O
c
C+12O2⟶CO
d
CO+12O2⟶CO2
answer is C.
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Detailed Solution
C(s)+12O2(g)⟶CO(g);ΔS increases.Hence, as the temperature increases, TΔS increases and hence ∆G (∆H -TΔS) decreases. In other words, the slope of the curve for formation of CO decreases. However, for all other oxides, it increases.