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Q.

ΔfGΘ vs T plot in the Ellingham diagram slopes downward for the reaction

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a

Mg+12O2⟶MgO

b

2Ag+12O2⟶Ag2O

c

C+12O2⟶CO

d

CO+12O2⟶CO2

answer is C.

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Detailed Solution

C(s)+12O2(g)⟶CO(g);ΔS increases.Hence, as the temperature increases, TΔS increases and hence ∆G (∆H -TΔS) decreases. In other words, the slope of the curve for formation of CO decreases. However, for all other oxides, it increases.
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