Q.

According to CFT for d6 configuration in an octahedral complex,  the correct possible electronic configurations  for complex with strong field ligands and with weak  field ligands respectively will be

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a

t2g4eg2 ;  t2g6

b

t2g6 ;  t2g4eg2

c

t2g2eg4 ;   t2g3eg3

d

t2g3eg3 ; t2g2eg4

answer is B.

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Detailed Solution

In octahedral complexes, energy of  t2g  P,strong field ligand, Pairing occurs in lower level until it is completely –  t2g6Δo < P,weak field ligand, Pairing occurs only when both t2g and eg set of orbitals are half filled…… t2g4eg2
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