According to werner theory secondary valency of central atom in Pt(en)(H2O)2Cl2Cl2 Complex is satisfy by fallowing species

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en,H2O and Cl-

H2O

en, and H2O

answer is B.

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Detailed Solution

1 en (bidentate ligand) and 2Cl-, 2H2O ligands are directly donate the electron pair towards central metal atom Pt, so coordination number satisfy the secondary valency. Hence secondary valency Pt(en)(H2O)2Cl2Cl2 Complex is 6

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