A = AcetaldehydeB = AcetoneC = Di-tert-butyl ketoneD = Methyl tert -butyl ketone Decreasing order of reactivity towards HCN is
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a
A > B > C > D
b
C > D > B > A
c
A > B > D > C
d
C > B > A > D
answer is C.
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Detailed Solution
As number and size of alkyl groups attached to carbonyl groups increases +I effect and steric hindrance increases. Carbonyl carbon becomes less electrophilic,reactivity decreases.