In acidic medium the rate of reaction between BrO3- and Br− ion is given by the expressiond(BrO3-)dt = K [BrO3-] [Br−] [H+]2Which of the following is correct?
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a
Doubling the concentration of H+ ions will increase the reaction rate by 4 times.
b
Rate constant of overall reaction is 4 sec−.
c
Rate of reaction is independent of the conc. of acid
d
The change in pH of the solution will not affect the rate.
answer is A.
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Detailed Solution
For the reaction,d[BrO3-]dt=K [BrO3-] [Br−] [H+]2The rate law equation contains [H+]2 , term. The rate will change with change in pH and new rate will be [2]2=4 times the old rate