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Q.

In acidic medium the rate of reaction between BrO3- and Br− ion is given by the expressiond(BrO3-)dt = K [BrO3-]  [Br−]  [H+]2Which of the following is correct?

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a

Doubling the concentration of H+ ions will increase the reaction rate by 4 times.

b

Rate constant of overall reaction is 4 sec−.

c

Rate of reaction is independent of the conc. of acid

d

The change in pH of the solution will not affect the rate.

answer is A.

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Detailed Solution

For the reaction,d[BrO3-]dt=K [BrO3-] [Br−] [H+]2The rate law equation contains [H+]2 , term. The rate will change with change in pH and new rate  will be [2]2=4 times the old rate
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