Q.

On adding excess of AgNO3 solution into 0.01 mole complex compound PtBr4⋅xNH3, 0.03 moles yellow precipitate was obtained, then value of 'x' is :

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a

2

b

3

c

4

d

5

answer is D.

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Detailed Solution

PtBr4⋅xNH3+AgNO3 solution ⟶AgBr↓0.01 mole  Excess 0.03 moles ∴ The value of x = 5 i.e., complex is [ PtBrNH35Br3
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On adding excess of AgNO3 solution into 0.01 mole complex compound PtBr4⋅xNH3, 0.03 moles yellow precipitate was obtained, then value of 'x' is :