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Q.

Adsorption is spontaneous and proceeds with decrease in entropy. Hence, which is correct representation of variation of xmwith pressure at different temperature?

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a

b

c

d

answer is A.

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Detailed Solution

Adsorption is spontaneous, thus ΔG<0.It proceeds with decrease in entropy, thus ΔS<0Since,                  ΔG=ΔH−TΔS                           ΔH=(ΔG+TΔS)                           ΔG and ΔS being <0thus,                   ΔH<0By Le-Chatelier's principle, increase in temperature, decreases adsorption Also, xm∝ p, but extent of adsorption decreases as T increases.
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