Adsorption is spontaneous and proceeds with decrease in entropy. Hence, which is correct representation of variation of xm with pressure at different temperature?
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answer is A.
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Detailed Solution
Adsorption is spontaneous, thus ∆G<0It proceeds with decrease in entropy, thus ∆S<0Since, ΔG=ΔH−TΔS ΔH=(ΔG+TΔS) ΔG and ΔS beìng <0Thus, ΔH<0By Le-Chatelier's principle, increase in temperature, decreasesadsorption. Also xm ∝ p, but extent of adsorption decreasesas T increases.