Q.

AlCl3 is an electron-deficient compound but AlF3 is not, due to

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a

Atomic size of F is smaller than Cl, which makes AlF3, more covalent.

b

AlCl3 is a covalent compound while AlF3 is an ionic compound.'

c

Al in AlCl3 is sp3 hybridised but in AlF3,Al is sp3 hybridised.

d

AlCl3 exists as a dimer but AlF3 does not.

answer is B.

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Detailed Solution

There is this rule called as Fajan's rule which states that with increasing size of the anion and with decreasing size of the cation ionic character of the compound decreases while the covalent character increases.Here, since the cation is same in both the compounds, the size of the anion decides the nature of the compound. Size of chlorine being greater than fluorine, AlCl3​ is covalent while AlF3​ is ionic.
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