Alcohols (i) CH3CH2CH2OH (ii) CH3−CHOH−CH3 and (iii) CH3−CCH3OH−CH3 were treated with Lucas reagent (Conc. HCI + ZnCI2). What results do you expect at room temperature?

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(ii) and (iii) react immediately and (i) in about 5 minutes

(iii) reacts immediately, (ii) reacts in about 5 minutes and (i) not at all

(i) reacts immediately, (ii) reacts in about 5 minutes and (iii) not at all

(i) reacts in about 5 minutes, (ii) reacts in about 15 minutes and (iii) not at all

answer is B.

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Detailed Solution

rate of reaction of alcohols with Lucas reagent is 3o > 2o > 1o

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