Q.

In alkaline medium,H2O2 reacts with Fe+3 and Mn+2 separately to give:

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a

Fe+4 and  Mn4+

b

Fe+2 and  Mn+2

c

Fe+2 and  Mn+4

d

Fe4+ and  Mn+2

answer is C.

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Detailed Solution

K3FeCN6 is reduced by H2O2 in alkaline medium 2K3FeCN6+2KOH+H2O2→  2K4FeCN6+2H2O+O2MnOH2 is oxidised by H2O2 in alkaline medium MnOH2+H2O2→MnO2+2H2O
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