Q.

The alkane that gives only one mono-chloro product on chlorination with Cl2 in presence of diffused sunlight is

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a

Isopentane

b

2, 2-dimethylbutane

c

neopentane

d

n-pentane

answer is C.

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Detailed Solution

Chlorination of neopentane with Cl2 in the presence of diffused sunlight gives only one mono-chloro compound.All hydrogens in neopentane are structurally and stereochemically are equivalent.
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The alkane that gives only one mono-chloro product on chlorination with Cl2 in presence of diffused sunlight is