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Aluminium chloride in acidified aqueous solution forms a complex 'A', in which hybridisation state of Al is 'B'. What are 'A' and 'B', respectively?

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By Expert Faculty of Sri Chaitanya
a
AlH2O63+, d2sp3
b
AlH2O63+, sp3 d2
c
AlH2O43+, sp3
d
AlH2O43+, dsp2

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detailed solution

Correct option is B

∴ The hybridization of Al is sp3d2 .


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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