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Aluminium chloride in acidified aqueous solution forms a complex ‘X’. Hybridization of ‘Al’ in the complex is

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a
sp3d
b
sp3
c
dsp2
d
sp3d2

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detailed solution

Correct option is D

The complex formed is [Al(H2O)6]Cl3 (or) AlCl3.6H2OHybridization of ‘Al’ in [Al(H2O)6]+3 is sp3d2. The complex has octahedral geometry.


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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