Q.
Aluminium oxide may be electrolysed at 1000oC to furnish aluminium metal (Atomic Mass = 27 amu; 1F = 96,500 C). The cathode reaction is Al3++3e−→AlTo prepare 5.12 kg of aluminium metal by this method would require
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a
5.49×104C
b
1.83×107C
c
5.49×107C
d
5.49×101C
answer is C.
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Detailed Solution
27 g of Al is obtained by passing a current of 3×96500 C.∴ 1 g of Al is obtained by passing a current of 3×9650027C. ∴ 5.12×103 g of Al is obtained by passing a current of 3×9650027×5.12×1000 =1.83×107C×3=5.49×107C
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