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Q.

An amine on reaction with benzenesulphonyl chloride produces a compound insoluble in alkaline solution. This amine can be prepared by ammonolysis of ethyl chloride. The correct structure of amine is:

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a

b

c

CH3CH2CH2NH2

d

CH3CH2NH2

answer is B.

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Detailed Solution

A 2° amine gives a product insoluble in alkaline solutions when treated with C6H5SO2ClBut the 2° amine is obtained by ammonolysis of ethyl chloride .∴The 2° amine has to be CH3−CH2−CH2−NH−CH2CH3

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