Ammonium carbonate when heated to 2000C gives a mixture of NH3 and CO2 vapour with a density of 13.0. What is the degree of dissociation of ammonium carbonate?
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a
3/2
b
1/2
c
2
d
1
answer is D.
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Detailed Solution
NH2COONH4 ⇌ 2NH3 + CO2α = D-dn -1d where d is the density (initial)D=vapour density=mol.wt2 = 782 = 39n =Total no. of moles of products= 3, d = final densityα = 39-133 -113=1, so α=1