Q.

Among the following, the azeotropic mixture is

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a

CCI4+CHCI3

b

C6H14+C7H16

c

C2H5Br+C2H5Cl

d

chlorobenzene + bromobenzene

answer is A.

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Detailed Solution

Only non-ideal solutions form azeotropic mixtures (constant boiling mixtures). Among the given, only CCl4 and CHCI3 form non-ideal solution, thus they form azeotropicmixture.
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