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Q.

Among the following complexes, the ones that exhibit both geometrical and optical isomerism is (are)?

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a

[NiCl2(Ph3P)2]

b

[Co(NH2CH2COO)3]

c

[Fe(C2O4)2Cl2]3−

d

[PtClBr(NH3)(CH3NH2)]

answer is B.

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Detailed Solution

(2) has facial & meridional isomers & both exhibit optical isomerism.(3) has cis & trans isomers, cis being optically active. Another point is that plane of symmetry plays an important role in optical activity.
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Among the following complexes, the ones that exhibit both geometrical and optical isomerism is (are)?