Q.

Among the following, the number halide(s) which is / are inert to hydrolysis is ______.(i) BCl3                 (ii) SiCl4                  (iii)  PCl5                 (iv) SF6

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Detailed Solution

(1) BCl3+3H2O→H3BO3+3HCl (2) SiCl4+4H2O→SiO4H4+4HCl (3) PCl5+H2O→POCl3+2HCl(4) Due to steric crowding by six F-atoms, SF6 is inert towards hydrolysis.
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