Q.
Among the following, the number halide(s) which is / are inert to hydrolysis is ______.(i) BCl3 (ii) SiCl4 (iii) PCl5 (iv) SF6
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answer is 1.
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Detailed Solution
(1) BCl3+3H2O→H3BO3+3HCl (2) SiCl4+4H2O→SiO4H4+4HCl (3) PCl5+H2O→POCl3+2HCl(4) Due to steric crowding by six F-atoms, SF6 is inert towards hydrolysis.
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