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Q.

Among the following, the pair that is not a pair of metamers is

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a

CH3OCH2CH2CH3 & CH3CH2OCH2CH3

b

CH3OCH2CH2CH3 & CH3OCH(CH3)2

c

CH3NHCH2CH2CH3 & CH3CH2NHCH2CH3

d

CH3COCH2CH2CH3&CH3CH2COCH2CH3

answer is B.

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Detailed Solution

→ The structures which have same molecular formula but differ in nature and number alkyl chain on either side of bivalent functional group are called metamers and the phenomina is said to be metamerismExamples:→ The above two isomers differ in the position of –OCH3 group hence, they are positional isomers but not metamers, since carbon chain lengths are same.
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Among the following, the pair that is not a pair of metamers is