Among the following statement which one is true?

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NH3 is less soluble than PH3, in water

NH3 is sfronger base and stronger reducing agent thanPH3

NH3 , has higher boiling point than PH3 and has lower melting point than PH3

PH3 is stronger reducing agent than NH3 and it has lower critical temperature that NH3

answer is D.

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Detailed Solution

NH3 is a weak reducing agent than PH3 because X - H bond strength decreases down the group. Due to absence of H-bond only weak van der Waals force of attraction exists in PH3 Hence it has lower critical temperature than NH3

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