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Q.

Among the following statement which one is true?

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a

NH3 is less soluble than PH3 in water

b

NH3 is stronger base and stronger reducing agent than PH3

c

NH3 has higher boiling point than PH3 and has lower complex tendency than PH3

d

PH3 is stronger reducing agent than NH3 and it has lower boiling point than NH3

answer is D.

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Detailed Solution

NH3 is a weak reducing agent than PH3, because X - H bond strength decreases down the group. Due to absence of H-bond only weak van der Waals force of attraction exists in PH3, Hence it has lower critical temperature and lower boiling point than NH3.
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