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a
NH3 is less soluble than PH3 in water
b
NH3 is stronger base and stronger reducing agent than PH3
c
NH3 has higher boiling point than PH3 and has lower complex tendency than PH3
d
PH3 is stronger reducing agent than NH3 and it has lower boiling point than NH3
answer is D.
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Detailed Solution
NH3 is a weak reducing agent than PH3, because X - H bond strength decreases down the group. Due to absence of H-bond only weak van der Waals force of attraction exists in PH3, Hence it has lower critical temperature and lower boiling point than NH3.