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Q.

Among the following the strongest nucleophile is

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a

C2H5SH

b

CH3COO−

c

CH3NH2

d

NCCH2−

answer is A.

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Detailed Solution

Nucleophiles are those substances that can donate a pair of electrons. These can be neutral or negative. The nucleophilic power depends on the tendency of species to donate electrons. This is more, when an electron pushing group (+I group) is present. Among the alkyl groups, those having higher number of C-atoms will push more, hence, ethyl > methyl.
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Among the following the strongest nucleophile is