Q.
Among the following, which has the highest boiling point ?
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a
NH3
b
PH3
c
AsH3
d
CH4
answer is A.
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Detailed Solution
Inter molecular H-bonding increases the boiling point of the compound [ In NH3] Boiling point order :As the size of central element increases,molecular size increases, intermolecular attractions increases.Hence ,we need to provide high amount of energy in the form of boiling point [heat], Hence B.Pt increases form PH3 to SbH3.Exceptionally hight B.Pt of NH3 is due to its ability to form intermolecular hydrogen bonding.
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