Q.

Among the following, which has the highest boiling point ?

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a

NH3

b

PH3

c

AsH3

d

CH4

answer is A.

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Detailed Solution

Inter molecular H-bonding increases the boiling point of the compound [ In  NH3]  Boiling point order :As the size of central element increases,molecular size increases, intermolecular attractions increases.Hence ,we need to provide high amount of energy in the form of boiling point [heat],                   Hence B.Pt increases  form PH3 to SbH3.Exceptionally hight B.Pt of NH3 is due to its ability to form intermolecular hydrogen bonding.
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