Q.

Among the given salts, aqueous solution of which salt will show maximum freezing point?

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a

0.2 m NaCl (aq) (α = 80%)

b

0.4 m (aq) MgCl2 (α = 60%)

c

0.8 m CaCl2 (α = 30%)

d

0.6 m AlCl3 (α= 10%)

answer is A.

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Detailed Solution

∆Tf∝number of patricles∆Tf∝1Tf so ∝=i-1n-1                           0.8=i-12-1                              i=1.8 0.2m NaCl (aq) (α = 80%) solution has 0.2 x 1.8 = 0.36 value has least among all given options, hence minimum depression in freezing point and maximum freezing point.
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Among the given salts, aqueous solution of which salt will show maximum freezing point?