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Among the III A group elements, the difference in the atomic radius is large in between

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By Expert Faculty of Sri Chaitanya
a
Aluminium and Boron
b
Gallium and Aluminium
c
Thallium and Indium
d
Gallium and Indium

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detailed solution

Correct option is A

B - 1s2 2s2 2p1Al - 1s2 2s2 2p6 3s23p1From B to Al as the number of inner shell s and p- orbital electrons increases,shielding effect increases .Since s and p-orbital electrons acts as strong screens hence they can protect the valency electrons from the nucleus effectively,so nuclear forces of attractions on valency electrons decreases,therfore size increases largely from B to Al.


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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