Q.
Among KO2,AlO2-,BaO2 and NO2+, unpaired electron is present in
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a
NO2+ and BaO2
b
KO2 and AlO2-
c
KO2 only
d
BaO2 only
answer is C.
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Detailed Solution
In NO2+ odd (unpaired) electron is removed. In peroxides O22- no unpaired electrons are present as the antiboinding pi M.O.'s acquired one more electron each for pairing. AlO2- no unpiared electrons. Superoxide O2- has one un paired electron in pi antibonding M.O.