Q.
Amongest the elements of group-14, the oxidising power of the tetravalent species increases in the order.
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a
Ge < Pb < Sn
b
Ge < Sn < Pb
c
Pb < Ge < Sn
d
Sn < Ge < Pb
answer is B.
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Detailed Solution
Due to inert pair effect , the stability of '+4' oxidation state decreases & '+2' state increases down the group The order of stability is , Ge+4 > Sn+4 > Pb+4 The order of oxidizing power is , Ge+4 < Sn+4 < Pb+4 Hence in '+4' oxidation state lead acts as a good oxidizing agent and it self reduces to stable Pb+2In case of ' Ge & Sn ' +4 state is more stable than +2
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