Q.

Amongest the elements of group-14, the oxidising power of the tetravalent species increases in the order.

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a

Ge < Pb < Sn

b

Ge < Sn < Pb

c

Pb < Ge < Sn

d

Sn < Ge < Pb

answer is B.

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Detailed Solution

Due to inert pair effect , the stability of '+4' oxidation state decreases & '+2' state increases down the group  The order of stability is ,   Ge+4 > Sn+4 > Pb+4    The order of oxidizing power is ,  Ge+4 < Sn+4 < Pb+4 Hence in '+4' oxidation state lead acts as a good oxidizing agent and it self reduces to  stable Pb+2In case of ' Ge & Sn '  +4 state is more stable than +2
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Amongest the elements of group-14, the oxidising power of the tetravalent species increases in the order.