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Q.

Amongst the following statements regarding adsorption, those that are valid are :           (a) ΔHbecomes less negative as adsorption proceeds.           (b) On a given adsorbent, ammonia is adsorbed more than nitrogen gas.           (c) On adsorption, the residual force acting along the surface of the adsorbent increases.          (d) With increase in temperature, the equilibrium concentration of adsorbate increases.

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a

(b) and (c)

b

(a) and (b)

c

(c) and (d)

d

(d) and (a)

answer is B.

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Detailed Solution

During adsorption, after some time equilibrium is reached. Hence ΔH becomes less negative.           NH3 has more TC, hence more adsorbed than N2.   Due to adsorption, residual forces decrease.As T increases, xm decreases.         ∴ (a) & (b) are true.
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