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Q.

Aniline reacts with mixed acid (conc. HNO3and conc. H2SO4) at 288 K to give P (51%), Q R→             3)H3O+         4)NaNO2,HCl/273−2798K          5)EtOH,Δ1)Ac2O,pyridine2)Br2,CH3CO2HS→                     3)NaNO2,HCl/273−278K                      4)H3PO2        1)Sn/HCl      2)Br2/H2OexcessMajor  products

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a

b

c

d

answer is D.

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