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Q.

In an aqueous solution ferric ion gives blood red colour with potassium thiocyanate solution. Which of the following gives blood red colour with KSCN solution

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a

Fe4FeCN63

b

K3FeCN6

c

NH42SO4. FeSO4.6H2O

d

Fe3FeCN62

answer is A.

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Detailed Solution

Fe4FeCN63 ⇌ 4Fe+3+3FeCN6−4This solution contains free Fe+3 ion(2) & (4) --Fe+3 ion is in complex ion ….It cannot react with SCN– ion(3) Does’nt contain Fe+3 ion

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