Q.

An aqueous solution freezes at – 0.1860C (Kf = 1.860; Kb = 0.5120). What is the elevation on boiling point?

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answer is 4.

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Detailed Solution

Method I :     Given Tf(Fp of  sol.) = -0.186oc                            Kf = 1.86 K Kg mole-1       ,   Kb= 0.512 K Kg mole-1                             method-II :
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An aqueous solution freezes at – 0.1860C (Kf = 1.860; Kb = 0.5120). What is the elevation on boiling point?