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Q.

Aqueous solution of Ni2+ contains NiH2O62+ and its magnetic moment is 2.83 BM.When ammonia is added in it, comment on the magnetic moment of solution :

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a

It will remain same

b

It increases from 2.83 BM.

c

It decreases from 2.83 BM.

d

It cannot be predicted theoretically

answer is A.

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Detailed Solution

NiH2O62++6NH2⇌NiNH362++6H2O sp3d2 Hyb.                            sp3d2Hyb μeff=2.8BM                             μeff=2.8BM
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Aqueous solution of Ni2+ contains NiH2O62+ and its magnetic moment is 2.83 BM.When ammonia is added in it, comment on the magnetic moment of solution :