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In an aqueous solution of volume 500 ml, when the reaction of 2Ag+ + Cu ⇌ Cu2+ + 2Ag reached equilibrium the Cu2+ was x M. When 500 ml of water is further added, at the equilibrium Cu2+ will be

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a

2x M

b

x M

c

between x M and x/2 M

d

less than x/2 M

answer is D.

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Detailed Solution

2Ag+ + Cu ⇌ Cu2+ + 2Aga M x M if V is 500 mlIf volume is doubled, then for KC=xa2 to have same value Cu2+ will be less than x/2

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