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Q.

Arrange the following in decreasing order of reactivity towards Aromatic electrophilic substitution reaction

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a

I > II > III

b

II > I > III

c

III > II > I

d

III > I > II

answer is A.

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Detailed Solution

Heavier the isotope,stronger the bond formed by them,hence +ve hyper conjugation effect decreases,hence electron donation ability decreases,hence electron density in the ring decreases,therefore reactivity with respect to electrophile decreases.
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