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Q.

Arrange the following in order of increasing order of their stability.

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a

I>III>II>IV

b

IV>II>III>I

c

III>II>IV>I

d

IV>I>III>II

answer is B.

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Detailed Solution

+M effect of NH2 group disperses the charge of carbocation, hence, increases the stability and -CH3 group shows +I effect, hence, it will disperse the charge less than -NH2. C∙∙H is triplet carbine, which have least tendency to release electron, hence, makes the carbocation less stable. Whereas -NO2 group shows -M effect due to which the positive charge on the carbocation increases hence stability decreases.
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