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Q.

Arrange the following in their decreasing order of basic character.

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a

III > IV > I > II

b

I > II > III > IV

c

IV > III > II > I

d

II > III > I > IV

answer is A.

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Detailed Solution

(III) +I effect of two Me groups > (IV)  NH2> (I) EWG (C=O) group > (II) EWG two (C=O) groups.
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Arrange the following in their decreasing order of basic character.